Bifunctional dithiocarbamates: a bridge between coordination chemistry and nanoscale materials.
نویسندگان
چکیده
A dithiocarbamate-based methodology is employed to prepare linked heteromultimetallic complexes and then further exploited in the surface functionalisation of gold nanoparticles.
منابع مشابه
Perplexing Coordination Behaviour of Potentially Bridging Bipyridyl-Type Ligands in the Coordination Chemistry of Zinc and Cadmium 1,1-Dithiolate Compounds
The X-ray structural chemistry of zinc and cadmium 1,1-dithiolates (for example, xanthate, dithiophosphate and dithiocarbamate) with potentially bridging bipyridyl-type ligands (for example, 4,4′-bipyridine) is reviewed. For zinc, the xanthates and dithiophosphates uniformly form one-dimensional coordination polymers, whereas the zinc dithiocarbamates are always zero-dimensional, reflecting the...
متن کاملExploring the coordination chemistry of bifunctional organoarsonate ligands: syntheses and characterisation of coordination polymers that contain 4-(1,2,4-triazol-4-yl)phenylarsonic acid†
CrystEngComm PAPER Wolfgang Schmitt et al. Exploring the coordination chemistry of bifunctional organoarsonate ligands: syntheses and characterisation of coordination polymers that contain 4-(1,2,4-triazol-4-yl)phenylarsonic acid a This account describes the coordination chemistry of a novel bifunctional arsonic acid ligand, 4-(1,2,4-triazol-4-yl)phenylarsonic acid (H 2 TPAA) that contains a tr...
متن کاملSynthesis and Characterization of Nano-Structure Copper Oxide From Two Different Copper (II) Metal-Organic Framework Precursors
Nano-structured copper oxides were successfully prepared through direct calcination of 1D ladderlike metal-organic framework [Cu2(btec)(2,2'-bipy)2]∞, (btec = 1,2,4,5-benzenetetracarboxylate and 2,2'-bipy = 2,2'-bipyridine) and porous coordination polymer [Cu(BDC)(bipy)](BDCH2), (BDC = 1,4-benzenedicarboxylate; bipy = 4,4'-bipyridine). The nano-structure of the as-synthesized samples are charac...
متن کاملNanoscale spinel LiFeTiO4 for intercalation pseudocapacitive Li(+) storage.
Intercalation pseudocapacitive Li(+) storage has been recognized recently in metal oxide materials, wherein Li(+) intercalation into the lattice is not solid-state diffusion-limited. This may bridge the performance gap between electrochemical capacitors and battery materials. To date, only a few materials with desired crystal structure and with well-defined nanoarchitectures have been found to ...
متن کاملPreparation of Hexanitrohexaazaisowurtzitane (HNIW) Nano Particle by Normal Microemulsion Based Nonionic Surfactant
The behavior of nanoscale energetic materials is quite different from micronsized energetic materials in many ways. Recently, some techniques such as sol-gel method, high speed air impaction and vacuum codeposition have been employed to obtain nanoscale energetic materials. However, only few attentions were paid to nanoscale energetic materials because of the fabrication difficulty. In this pap...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Dalton transactions
دوره 4 شماره
صفحات -
تاریخ انتشار 2009